The Basic Degradation of D-ribo-Hexos-3-ulose and Isolation of 3-Deoxy-D-glycero-pentosulose.
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چکیده
منابع مشابه
Rearrangement of 3-deoxy-D-erythro-hexos-2-ulose in aqueous solution: NMR evidence of intramolecular 1,2-hydrogen transfer.
Selective (13)C- and (2)H-labeling, and (13)C NMR spectroscopy, have been used to show that the 1,2-dicarbonyl compound (osone), 3-deoxy-D-erythro-hexos-2-ulose (3-deoxy-D-glucosone) (1; 3DG), degrades to 3-deoxy-D-ribo-hexonic acid 2 and 3-deoxy-D-arabino-hexonic acid 3 exclusively via an intramolecular 1,2-hydrogen transfer mechanism in aqueous phosphate buffer at pH 7.5 at 37 °C. Acids 2 and...
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ژورنال
عنوان ژورنال: Acta Chemica Scandinavica
سال: 1971
ISSN: 0904-213X
DOI: 10.3891/acta.chem.scand.25-0883